Everything Everywhere Daily: History, Science, Geography & More - Transuranium Elements (Encore)

Starting point is 00:00:00 The following is an encore presentation of Everything Everywhere Daily. If you take a look at the periodic table of elements, you'll notice something interesting. Go to the bottom and take a look at any element over, say, number 94. You'll find a bunch of elements that you've probably never heard of. But don't worry, because most chemists probably aren't familiar with them either. They're not part of any chemical compounds, can't be found in nature, and most of them have only existed for a fraction of a second. Learn more about trans-uranium elements, what they are,

Starting point is 00:00:33 and how we even know they exist on this episode of Everything Everywhere Daily. What if your perceptions about the past were wrong? ThruLine is a podcast that takes you back in time to uncover the parts of the story that may have gone unnoticed. It effectively turned day into night. And how it shaped the world now. Time travel with us every week on the ThruLine podcast from NPR. Over the course of this podcast, I've done many episodes. on individual elements of the periodic table.

Starting point is 00:01:22 The episode will usually talk about its atomic configuration, how the element was discovered, and its various uses. The trans-uranium elements, however, are in a category all of their own. They barely exist naturally, are all highly unstable, and their very existence is due to human creation. With some minor exceptions, they don't have any use at all, and for the most part, they don't even exist, save for a tiny fraction of a second.

Starting point is 00:01:48 But let's start by explaining what a trans-uranium element is. The heaviest naturally occurring element in nature is uranium, with an atomic number of 92. Uranium isn't incredibly abundant, but it isn't hard to find in rocks in many places around the world. Having an atomic number of 92 means that there are 92 protons in the nucleus of the atom, and the number of protons is what determines what an element is. While each atom of an element have the same number of protons, different atoms can have different numbers of neutrons in the nucleus. Atoms with different number of neutrons are called isotopes.

Starting point is 00:02:28 In the case of uranium, there are two common isotopes that are found in nature, uranium 238 with 146 neutrons, and uranium 235 with 143 neutrons. Chemically, isotopes behave exactly the same. However, different isotopes will have different levels of atomic. stability. The more unstable an atom is, the more likely it is to undergo radioactive decay. There are only certain isotopes of any element that are stable. With the wrong configuration of protons and neutrons, it'll fall apart until the resulting configuration is stable. The statistical time it takes to fall apart is known as its half-life.

Starting point is 00:03:08 Extremely unstable atoms may have half-lives of just a fraction of a second. More stable atoms like uranium can have half-lives in the hundreds of millions to billions of years. The other thing to know for the purpose of this episode is that, in general, larger atomic nuclei tend to be more unstable. That's not to say that you can't have a rare isotope of a lighter element be unstable, but you usually won't find those in the environment because they've already decayed. So that brief explanation of nuclear physics aside, going into the 1940s, there were no known elements with an atomic number higher than uranium at 92. There was nothing found in nature that had an atomic number higher than that.

Starting point is 00:03:51 There were some claims of an element 93, but there was no proof. So as far as everybody knew, that may have been the heaviest element in the universe. However, in 1940, experiments were conducted with nuclear fission by a team led by Edwin McMillan and Hague Abelson at the University of California Berkeley, who bombarded uranium-230, with neutrons. This created uranium 239, which then decayed into a new element number 93. The element was dubbed Neptune because the planet Neptune is the one after Uranus. However, they realized that if element 93 existed, then it also must decay into element 94. Element 94 was discovered in 1941 by a man whose name is going to appear a lot in this episode,

Starting point is 00:04:38 Glenn Seaborg. Seaborg worked at Berkeley, and their process was very similar to that which discovered Neptuneium. I've previously done an entire episode on plutonium, but the one thing I'll add for this episode is that extremely trace amounts of plutonium and Neptuneium have been found naturally as the result of decay of uranium. However, the amounts are so small, literally scattered atoms that for all practical purposes, you can still say that uranium is the heaviest natural element.

Starting point is 00:05:09 The quest to create more elements continued. In 1944, as part of the Manhattan Project, Glenn Seaberg's team discovered element 96, curiam, named after Marie Curie, and Element 95, Ameritium, named after the United States. Both elements were created by exposing plutonium to either alpha radiation or neutron radiation. Both amyricium and curiam actually do have limited practical uses. Amaritium is sometimes used in smoke detectors as a source of ionizing radiation, and curium is sometimes used to kickstart fission chain reactions. What little that is needed is usually a byproduct of nuclear reactors.

Starting point is 00:05:48 This technique of exposing heavy elements to radiation continued to bear fruit in discovering new elements. Seaborg's team discovered Element 97 in 1949, Berkliam. This was created by exposing Amersinium to Alpha radiation, and then Element 98, California, was created by exposing curium to Alpha radiation. Berklium has no known use whatsoever, and Californium can be used in small amounts to also kickstart nuclear chain reactions because it is a strong neutron emitter. In 1951, Glenn Seaburg was awarded the Nobel Prize in Physics for his discovery of trans-uranium elements. However, this was nowhere near the end of the creation of elements with ever larger atomic numbers.

Starting point is 00:06:33 In 1952, researchers at Berkeley went through radioactive debris from hydrogen bomb tank. tests on Bikini Atoll. They discovered over 200 atoms of Element 99, which was dubbed Einsteinium, named after Albert Einstein. The next year, debris from a detonation on the Iwanitak Atoll showed evidence of Element 100, which was dubbed Fermium, after the nuclear pioneer in Rico Fermi. These two elements can be created in a nuclear reactor, but the higher up you go in atomic number, the more difficult it becomes by over an order of magnitude, along each step of the chain. For example, it takes 10 grams of curium

Starting point is 00:07:12 to make one picogram of fermium, and a picogram is one trillionth of a gram. All of these heavier elements are very radioactive with very short half-lives. It's entirely possible that these elements could have been created in a supernova, like all the heavy elements we experience on Earth, but they wouldn't have survived very long

Starting point is 00:07:33 because of their short half-lives. In 1955, Element 101, Mendelivium was discovered, which was created by bombarding Einsteinium with Alpha Radiation, and this was also created by Glenn Seberg and his team. By this time, exposing heavy elements to radiation had pretty much reached a dead end. A new technique was developed, which involved slamming trans-uranium elements with much larger atomic nuclei than just helium, which is what Alpha Radiation is. In 1961, the team at Berkeley discovered Element 103, Lorencinium by bombarding Californium with boron atoms. Pretty much every new discovery of a trans-uranium element at this point had been made at the University of California, Berkeley.

Starting point is 00:08:19 The next discovery was the first outside of the United States. In 1965, the Joint Institute for Nuclear Research in Dubna, outside of Moscow, discovered Element 102, Nobilinium by bombarding uranium with non-Nobtainium. by bombarding uranium with neon atoms. This element was named after Alfred Nobel, the founder of the Nobel Prize. In 1969, the Soviets created element 104, rutherfordium, created by bombarding

Starting point is 00:08:43 Californium with carbon atoms, and also created by bombarding plutonium with neon atoms. And this was named after Ernst Rutherford, who discovered the atomic nucleus. I should note at this point, the elements being created were extremely small in numbers, and they were all incredibly radioactive,

Starting point is 00:09:00 with very short half-lives. The first isotope of Rutherfordium created had a half-life of five seconds. This technique of bombarding atoms with other atoms to create new elements is the technique that's still pretty much used today. The Soviets created Element 105, Dubnium in 1970, named after the city where their research center was located in Russia.

Starting point is 00:09:24 Berkeley created Element 106 in 1974 called Seaborgium in honor of Glen Seaborg. After this, the next several new elements were created by researchers at the GSI Helmholtz Center for Heavy Ion Research in Darmstadt, Germany. In 1981, they created Element 107, Borium, named after Neels Bohr. In 1982, they created Element 109, Mitenerian, named after Liza Maitner, one of the discoverers of Atomic Vision. In 1984, they made Element 108, Hasnium, named after the German state of Hesse. A decade later in 1994, they created Element 110, Darmstadtium, after the city of Darmstadt, Germany, and Element 111, Rontium, named after Wilhelm Rontgen, the discoverer of X-rays.

Starting point is 00:10:09 In 1996, they created Element 112, Copernicum, named after the astronomer Copernicus. After almost 20 years of new element discoveries, the Crown returned to Russia and the Joint Institute for Nuclear Research. In 1999, they discovered Element 114, Flavarium, named, after the physicist Georgie Flyerov. In 2000, they discovered Element 116, Livermoryam, named after the Lawrence Livermore National Laboratory in California. In 2002, they created Element 118, Ogenesson,

Starting point is 00:10:39 after Yuri Ogonesian, the Russian counterpart of Glenn Seaberg. And you'll notice that the elements they discovered are not in order of atomic number. Element 115 was created in 2003, dubbed Moscovium after Moscow. Element 113 was independently discovered by the Russians and a team in Japan and was named Nihonium, after the Japanese name for Japan, and finally in 2009, the Russians created element 117, which was dubbed Tennessee, after the state of Tennessee, the home of Oak Ridge National Laboratory.

Starting point is 00:11:11 And that is all that's been discovered as of this recording. There are periodic tables out there with placeholders for the undiscovered elements from 119 all the way up to 168. So having read off this list of elements that literally nobody would bother memorizing unless you happen to work in the field of super heavy chemical elements, what's the point of all this? All of these elements, at least beyond Element 98, California, have half-lives so short that they only exist for a tiny fraction of a second, and quantities that are so small you couldn't even tell they existed without incredibly sensitive equipment. While I rattled off the discovery dates of these elements, other researchers have been searching for different isotopes of many of these elements to see how long their half-lives are. Most are incredibly short, but some are the better part of a minute or even several minutes long.

Starting point is 00:12:04 The first discovery of an element gets the headlines, but what people are really searching for is something that Glenn Seaberg dubbed the Island of Stability. The island of stability would be some heavy element, or more accurate, a particular isotope of a heavy element that would be relatively stable or at least have a very long half-life. The problem with heavy atoms is that inside the nucleus there are two opposing forces at work. The electro-weak force wants to push protons apart because they have the same electrical charge. However, the strong nuclear force binds them together. Over very short distances, and I do mean very short, the strong force is more powerful than the electro-week

Starting point is 00:12:48 force, and thus the nucleus of an atom can exist. However, as an atomic nucleus gets bigger, the distance between some of the protons increases, decreasing the strength of the strong nuclear force. And this is believed to be why large atoms tend to be so unstable. It's believed, or at least hoped, that a configuration of neutrons exists that would provide stability to a large atom. Based on the mathematics of how isotopes of other atoms behave, it's thought that one of the best hopes for a stable, large atom would be an isotope somewhere in the elements 114, 120, or 126. However, 120 and 126 haven't been discovered yet, but researchers in Dubna, Russia, are working on creating 119 and 120 as I record this. If an island of stability could be

Starting point is 00:13:39 found. It could usher in a new understanding of the atom, as well as maybe a new era in material science. Finding the island of stability, if it even exists, will take a lot of work in a lot of time. So the next time you take a look at the periodic table, look down near the bottom, and give a moment to the elements that were created in a laboratory, only to exist for a fraction of a second. The executive producer of Everything Everywhere Daily is Charles Daniel. The associate producers are Austin Oakden and Cameron Kiefer. I want to thank everyone who supports the show over on Patreon. Your support helps make this podcast possible.

Starting point is 00:14:19 I'd also like to thank all the members of the Everything Everywhere community who are active on the Facebook group and the Discord server. If you'd like to join in the discussion, there are links to both in the show notes. And as always, if you leave a review or send me a boostagram, you two can have it read on the show.

Everything Everywhere Daily: History, Science, Geography & More - Transuranium Elements (Encore)

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