I Can’t Sleep - Laundry Detergent | Calm Bedtime Reading for Sleep
Episode Date: August 20, 2025Drift off with a calm, slow-paced bedtime reading about laundry detergent. Learn how tiny soap molecules lift dirt, the history of washing, and the quiet science of cleaning — all while your mind... relaxes. Benjamin Boster reads in a natural, soothing cadence — no whispering, no hypnosis, just gentle, fact-filled education that helps ease insomnia, stress, and late-night anxiety. Press play and let this sleep podcast carry you peacefully into rest. Want More? Request a Topic: https://www.icantsleeppodcast.com/request-a-topic Ad-Free Episodes: https://icantsleep.supportingcast.fm/ Shop Sleep-Friendly Products: https://www.icantsleeppodcast.com/sponsors Join the discussion on Discord: https://discord.gg/myhGhVUhn7 This content is derived from the Wikipedia article on Laundry detergent, available under the Creative Commons Attribution-ShareAlike (CC BY-SA) license. Read the full article: Wikipedia - Laundry detergent. Learn more about your ad choices. Visit megaphone.fm/adchoices
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Welcome to the I Can't Sleep podcast where I help you drift off one fact at a time.
I'm your host, Benjamin Boster.
Today's episode is about laundry detergent.
Remember to follow the show so you never miss an episode.
Laundry detergent is a type of detergent or cleaning agent used for cleaning dirty laundry or clothes.
Laundry detergent is manufactured in powder, washing powder, and liquid form.
While powdered and liquid detergents hold roughly equal share of the worldwide laundry detergent market in terms of value,
powder detergents are sold twice as much compared to liquids in terms of volume.
From ancient times, additives were used to facilitate the mechanical washing of textile fibers with water.
The earliest recorded evidence of the production of soap-like materials dates back to around 2,800 BC in ancient Babylon.
German chemical companies developed an alkalsulfate surfactant in 1917
in response to shortages of soap ingredients during the allied blockade of Germany during World War I.
In the 1930s, commercially viable routes to fatty alcohols were developed,
and these new materials were converted to their sulfate esters,
key ingredients in the commercially important German brand FIWA,
F-E-W-A, produced by BASF and DREF.
the U.S. brand produced by Procter & Gamble.
Such detergents were mainly used in industry until after World War II.
By then new developments and the later conversion of aviation fuel plants to produce tetrapropylene
used in household detergents production caused a fast growth of domestic use in the late 1940s.
washing laundry involves removing mixed soils from fiber surfaces.
From a chemical viewpoint, soils can be grouped into the following.
Water-soluble soils such as sugars, inorganic salts, urea, and perspiration.
Solid particulate soils such as rust, metal oxides, soot, carbon, black, carbonates, silicates, and hummus.
Hydrophobic soils such as animal fats, vegetable oils, sebum, mineral oil, and grease.
Proteins such as blood, egg, milk, and keratin from skin.
These require enzymes, heat, or alkali to hydrolyze and denature them
into smaller parts before they can become removed by surfactants.
Bleachable stains, such as wine, cough,
coffee tea, fruit juices, and vegetable stains.
Bleaching is an oxidation reaction, which turns a colored substance into a colorless one,
which either stays in the fabric, or maybe easier to wash out.
Soils difficult to remove are pigments and dyes, fats, resins, tar, waxes, and denatured protein.
Laundry detergents may contain builders.
50% by weight approximately.
Surfactants, 15%, bleach 7%, enzymes 2%,
soil antideposition agents, foam regulators, corrosion inhibitors, optical brighteners,
dye transfer inhibitors, fragrances, dyes, fillers, and formulation aids.
Builders, also called keylating or sequestering agents, are water softeners.
Most domestic water supplies contain some dissolved minerals, especially in hard water areas.
The metal cat ions present in these dissolved minerals, particularly calcium and magnesium ions,
can react with surfactants to form soapscomb, which is much less effective for cleaning,
and can precipitate onto both fabric and washing machine components.
Builders remove mineral ions responsible for hard water
through precipitation, keelation, or ion exchange.
In addition, they help remove soil by dispersion.
The earliest builders were sodium carbonate, washing soda,
and sodium silicate, waterglass.
In the 1930s, phosphates, sodium phosphates, and polyphosphates, sodium hexametaphate, were introduced.
Continuing was the introduction of phosphates, HEDP, ATMP, ED-TMP.
While these phosphorus-based agents were generally non-toxic, they are now known to cause nutrient pollution,
which can have serious environmental consequences.
As such, they have been banned in many countries,
leading to the development of phosphorus-free agents,
such as polycarboxylates, E-D-T-A, N-T-A,
citrates, trisodium citrate,
silicates, sodium-silicate,
gluconic acid, and polyacrylic acid,
or ion exchange agent.
like zeolites. Alkalide builders may also enhance performance by changing the pH of the wash.
Hyrophilic fibers like cotton will naturally have a negative surface charge in water,
whereas synthetic fibers are comparatively neutral. A negative charge is further increased by the
absorption of anionic suffractants. With increasing pH, soil and fibers become more negatively
charged, resulting in increased mutual repulsion.
The optimum pH range for good detergency is 9 to 10.5.
Alkalize may also enhance wash performance via the suponification of fats.
Builder and surfactant work synergistically to achieve soil removal, and the washing effect
of the builder may exceed that of the surfactant.
With hydrophilic fibers like cotton, wool, polyamide and polyacrylinitril, sodium triphosphate,
removes soil more effectively than a surfactin alone.
It is expected that when washing hydrophobic fibers, like polyester's and polyolephins,
the effectiveness of the surfactant surpasses that of the builder.
However, this is not the case.
surfactants are responsible for most of the cleaning performance in laundry detergent.
They provide this by absorption and emulsification of soil into the water,
and also by reducing the water's surface tension to improve wetting.
Laundry detergents contain mostly anionic and non-ionic surfactants.
Cadyonic surfactants are normally incompatible with anionic detergents,
and have poor cleaning efficiency.
They're employed only for certain special effects
as fabric softeners, anti-static agents, and biocides.
Zwitter ionic surfactants are rarely employed in laundry detergents,
mainly for cost reasons.
Most detergents use a combination of various surfactants
to balance their performance.
Until the 1950s, soap was the production.
dominant surfactant in laundry detergents. By the end of the 1950s, so-called synthetic detergents,
scindates, like branched alkalobenzene sulfonates, had largely replaced soap in developed countries.
Due to their poor biodegradability, these branched alkyl benzene sulfates were replaced with
linear alkabenzine sulfates, LAS, in the mid-1960s.
Since the 1980s, alcohol sulfates such as SDS have found increasing application at the expense of LAS.
Since the 1970s, non-ionic surfactants, like alcohol athoxylates, have acquired a higher share in laundry detergents.
In the 1990s, glucomides appeared as co-surfactants and alkaloglycicides,
have been used in specialty detergents for fine fabrics.
Despite the name, modern laundry bleaches do not include household bleach, sodium, hypochlorite.
Laundry bleaches are typically stable adducts of hydrogen peroxide, such as sodium perforate
and sodium precarbonate.
These are inactive as solids, but will release hydrogen peroxide upon exposure to water.
The main targets of bleaches are oxidizable organic stains,
which are usually of vegetable origin, e.g. chlorophyll, anthocyanidyes, tannins,
humic acids, and carotenoid pigments.
Hydrogen peroxide is insufficiently active as a bleach at temperature below 60 degrees Celsius,
which traditionally made hot washes the norm.
The development of bleach activators in the 1970s and 1980s
allowed for cooler washing temperatures to be effective.
These compounds, such as tetraacetyl-ethylacillacilline-diamine, T-A-E-D,
react with hydrogen peroxide to produce parasitic acid,
which is an even more effective bleach,
particularly at lower temperatures.
The use of enzymes for laundry was
introduced in 1913 by Otto Rome. The first preparation was a pancreatic extract obtained from
animals, which was unstable against alkali and bleach. Only in the latter part of the
century with the availability of thermally robust bacterial enzymes did this technology become
mainstream. Enzymes are required to degrade stubborn stains composed of proteins, e.g. milk,
cocoa, blood, egg yolk, grass. Fats, e.g. chocolate, fats, oils, starch, e.g. flour and potato stains.
And cellulose, damaged cotton fibrils, vegetable and fruit stains.
Each type of stain requires a different type of enzyme. Proteases, savenase, for proteins,
lipases for greases, eamilases for carbohydrates, for carbohydrates,
and cellulases for cellulose.
Many other ingredients are added depending on the expected circumstances of use.
Such additives modify the foaming properties of the product
by their stabilizing and counteracting foam.
Other ingredients increase or decrease the viscosity of the solution
or solubilize other ingredients.
Corrosion inhibitors counteractylize.
act damage to washing equipment.
Die transfer inhibitors prevent dyes from one article from coloring other items.
These are generally polar water-soluble polymers, such as polyvinyl pyrolidin, to which
the dyes preferentially bind.
Anti-reidaposition agents, such as carboxymethyl cellulose, are used to prevent fine soil particles
from reattaching to the product being cleaned.
commercial or industrial laundries may make use of a laundry sour during the final rinse cycle
to neutralize any remaining alkalis surfactants and remove acid-sensitive stains.
A number of ingredients affect aesthetic properties of the item to be cleaned
or the detergent itself before or during use.
These agents include optical brighteners, fabric softeners, and colorants.
A variety of perfumes are also components of modern detergents,
provided that they are compatible with other components,
and do not affect the color of the cleaned item.
The perfumes are typically a mixture of many compounds.
Common classes include terpine alcohols,
and their esters, aromatic aldehydes, and synthetic musks.
Worldwide, while liquid and powder detergents hold roughly,
equal market share in terms of value, powdered laundry detergent is more widely used. In 2018,
sales of powder detergent measured 14 million metric tons, double that of liquids. While liquid
detergent is widely used in many Western countries, powdered detergent is popular in Africa, India,
China, Latin America, and other emerging markets. Powderes also hold significant,
market share in Eastern Europe, and in some Western European countries, due to their advantage over
liquids and whitening clothes. According to Desme Belestra, designer and builder of chemical plants
and detergent making equipment, powder detergents have a 30 to 35 percent market share in Western Europe.
According to Lubrizol, the powder detergent market is growing by 2% annually.
Phosphates in detergent became an environmental concern in the 1950s and the subject of bans in later years.
Phosphates make laundry cleaner, but also cause eutrophication, particularly with poor wastewater treatment.
In 2013, an academic study of fragranced laundry products found more than 25 VOCs emitted from drier vents,
with the highest concentrations of acetaldehyde, acetone, and ethanol.
Seven of these VOCs are classified as hazardous air pollutants, HAPs, and two as carcinogenic HAPs.
The EEC Directive, 73-404 EEC, stipulates an average biodegradability of at least 90% for all types of surfactants used in detergents.
The phosphate content of detergents is regulated in many countries,
e.g. Austria, Germany, Italy, the Netherlands, Norway, Sweden, Switzerland,
United States, Canada, and Japan.
Laundry is the washing of clothing and other textiles, and more broadly, they're drying and iron in as well.
Laundry has been part of history since humans began to wear clothes,
so the methods by which different cultures have dealt with this universal human need
are of interest to several branches of scholarship.
Laundry work has traditionally been highly gendered,
with the responsibility in most cultures falling to women,
formerly known as laundresses or washerwomen.
The Industrial Revolution gradually led to mechanized solutions to laundry work,
notably is a washing machine and later is a tumble dryer.
Laundry, like cooking and child care, is still done both at home and by commercial establishments outside the home.
The word laundry may refer to the clothing itself or to the place where the cleaning happens.
An individual home may have a laundry room.
A utility room includes but is not restricted to the function of washing clothes.
An apartment building or student hall of residence may have a shared laundry facility, such as a Tsetsuga.
A standalone business is referred to as a self-service laundry, laundrette in British English, or laundromat in North American English.
Laundry was first done in water courses, letting the water carry away the materials which could cause stains and smells.
Laundry is still done this way in the rural regions of poor countries.
Agitation helps remove the dirt, so the laundry was rubbed, twisted, or slapped against flat rocks.
One name for this surface is a beetling stone related to beetling, a technique in the production of linen.
One name for a wooden substitute is a battling block.
The dirt was beaten out with a metaling.
the wooden implement, known as a washing paddle, battling stick, bat, beetle, or club.
Wooden or stone scrubbing surfaces set up near a water supply are gradually replaced by portable
rubboards, eventually factory-made corrugated glass or metal washboards. Once clean, the clothes
were rung out, twisted to remove most of the water. Then they were hung up on poles or clothes
lines to air dry, or sometimes just spread out on clean grass, bushes, or trees. Before the advent of
the washing machine, laundry was often done in a communal setting. Villages across Europe that could
afford it build a washhouse, sometimes known by the French name of Lavoir. Water was channeled
from a stream or spring, and fed into a building, possibly just a roof with no walls.
This washhouse usually contained two basins, one for washing and the other for rins,
through which the water was constantly flowing, as well as a stone lip inclined towards the water,
against which the wet laundry could be beaten. Such facilities were more comfortable and convenient
than washing in a water course.
Some lavoires had the wash basins at waste height,
although others remained on the ground.
The launders were protected to some extent from rain,
and their travel was reduced,
as the facilities were usually at hand in the village,
or at the edge of a town.
These facilities were public and available to all families,
and usually used by the entire village.
Many of these village were public,
washhouses are still standing, historic structures with no obvious modern purpose.
The job of doing the laundry was reserved for women who washed all their family's laundry.
Washer women, or laundresses, took in the laundry of others, charging by the piece.
As such, washhouses were an obligatory stop in many women's weekly lives, and became a sort of
institution or meeting place.
It was a women-only space where they could discuss issues or simply chat.
Indeed, this tradition is reflected in the Catalan idiom for suffrage, literally to do the
laundry, which means to gossip.
European cities also had public washhouses.
The city authorities wanted to give the poor population who would otherwise not have access
to laundry facilities the opportunity to work.
wash their clothes.
Sometimes these facilities were combined with public baths.
The aim was to foster hygiene and thus reduce outbreaks of epidemics.
Sometimes large metal cauldrons of washed copper, even when not made of that metal,
were filled with fresh water and heated over a fire, as a hot or boiling water is more
effective than cold in removing dirt.
a posseer could be used to agitate clothes in a tub.
A related implement called a washing dolly is a wooden stick or mallet
with an attached cluster of legs or pegs that moves the cloth through the water.
The Industrial Revolution completely transformed laundry technology.
Christina Hardiman, in her history from the Great Exhibition of 1851,
argues that it was the development of domestic machinery that led to women's liberation.
The mangle, or ringer, in American English, was developed in the 19th century,
two long rollers in a frame and a crank to revolve them.
A laundry worker took sopping wet clothing and cranked it through the mangle,
compressing the cloth and expelling the excess water.
The mangle was much quicker than hand-twisting.
It was a variation on the box mangle used primarily for pressing and smoothing cloth.
Meanwhile, 19th century inventors further mechanized the laundry process
with various hand-operated washing machines to replace tedious hand-rubbing against a washboard.
Most involved turning a handle to move paddles inside a tub.
Then some early 20th century machines used an electrically powered agitator.
Many of these washing machines were simply a tub on legs, with a hand-operated mangle on top.
Later, the mangle too was electrically powered, then replaced by a perforated double tub,
which spun out the excess water in a spin cycle.
Laundry drying was also mechanized with closed dryers.
dryers were also spinning perforated tubs, but they blew heat air rather than water.
In the late 19th and early 20th century, Chinese immigrants to the United States and to Canada
were well represented as laundry workers.
Discrimination, lack of English language skills, and lack of capital kept Chinese immigrants out of most desirable careers.
Around 1900, one and four ethnic Chinese men in the United States,
the U.S. worked in a laundry, typically working 10 to 16 hours a day. Chinese people in New York
City were running an estimated 3,550 laundries at the beginning of the Great Depression. In 1933,
the city's board of aldermen passed a law, clearly intended to drive the Chinese out of the business,
among other things, it limited ownership of laundries to U.S. citizens. The Chinese consolidated
benevolent association tried fruitlessly to fend this off, resulting in the formation of the
openly leftist Chinese Hand Laundry Alliance, CHLA, which successfully challenged this provision of
the law, allowing Chinese laundry workers to preserve their livelihood. The CHLA went on to function
as a more general civil rights group. Its numbers declined strongly after it was targeted by the FBI
during the second Red Scare,
1947 to
from 1850 to 1910,
Zulu men took on the task of laundering
the clothes of Europeans,
both Boers and British.
Laundering recalled
the specialist craft of
hide dressing, in which
Zulu males engaged in easing
Yonga, a prestige occupation
that paid handsomely.
They created a guild structure
similar to a union,
to guard their conditions and wages, involving into one, if not indeed, the most powerful group of African workmen in 19th century Natal.
In India, laundry was traditionally done by men.
A washerman was called Adobiwala, and Dobie became the name of their caste group.
A laundry place is generally called Adopi God.
This has given rise to place names where they work or work.
Laundry processes include washing, usually with water containing detergents or other chemicals,
agitation, rinsing, drying, pressing, or ironing, and folding.
The washing will sometimes be done at a temperature above room temperature
to increase the activities of any chemicals used and the solubility of stains,
and high temperatures kill microorganisms that may be present on the fabric.
However, it is advised that cotton be washed at a cooler temperature to prevent shrinking.
Many professional laundry services are present in the market, which offers at different price ranges.
Agitation helps remove dirt, which is usually mobilized by surfactants from between fibers.
However, due to the small size of the pores and fibers, the stagnant core of the fibers themselves see virtually no flow.
The fibers are nevertheless rapidly cleaned by diffusiaveresis, carrying dirt out into the clean water during the rinsing process.
Various chemicals may be used to increase the solvent power of water, such as the compounds in soap root or yucca root, used by Native American tribes.
Or the ash lye, usually sodium hydroxide or potassium hydroxide, once widely used for soaking laundry and urine.
So, a compound made from lye and fat, is an ancient and common laundry aid.
Modern washing machines typically use synthetic powdered or liquid laundry detergent
in place of more traditional soap.
Dry cleaning refers to any process which uses a chemical solvent other than water.
The solvent used is typically tetrachloroethylene, which the industry calls perk.
It is used to clean delicate fabrics that cannot withstand the rough and tumble of a washing machine and clothes dryer.
It can also obviate labor-intensive hand-washing.
In some parts of the world, including North America, apartment buildings and dormitories, often have laundry rooms,
where residents share washing machines and dryers.
Usually the machines are set to run only when money is put in a coin slot.
In other parts of the world, including Europe, apartment buildings with laundry rooms are uncommon,
and each apartment may have its own washing machine.
Those without a machine at home or the use of a laundry room
must either wash their clothes by hand or visit a commercial self-service laundry,
laundromat, laundrette, or a laundry shop.
A clothes dryer, tumble dryer, drying machine, or simply drier,
is an electric household appliance used to be used.
to remove moisture from loaded clothes, linens, and other textiles, usually after washing them
in a washing machine.
In the United States and Canada, more than 80% of all homes have clothes dryers.
The manual closed dryer was created in 1800 by M. Pocin from France.
Henry W. Altorfer invented and patented the electric clothes dryer in 1937.
J. Ross Moore, a North Dakota.
inventor, designed automatic clothes dryers, and published his electric dryer design in 1938.
Industrial designer Brooke Stevens designed an electric dryer with a glass window in the early 1940s.
Sometimes dryers are integrated with the washing machine in the form of washer dryer combos,
which are essentially a front-loading washing machine with a built-in dryer,
or in the U.S. a laundry center,
which mounts a dryer on top of the washing machine
and combines the controls for both machines into one control panel.
Often the washer and dryer functions have different capacities,
with the dryer usually having a lower capacity than the washer.
Laundry dryers can also be top loading,
in which the drum is loaded from the top of the machine
and the drum and supports are on the left and right sides.
rather than the more traditional front and back sides of the machine they can be up to forty centimeters wide and can include removable stationary shelves for drying things like stuffed toys and shoes
