Planetary Radio: Space Exploration, Astronomy and Science - Why is Mars red? A new clue to the history of habitability in Martian dust
Episode Date: April 9, 2025For decades, scientists hypothesized that Mars’ reddish color came from hematite, an iron oxide thought to have formed through dry oxidation after Mars lost its water. But new research suggests ...the story is more complex—and more watery—than we once imagined. In this episode, planetary scientist Adomas (Adam) Valantinas from Brown University joins host Sarah Al-Ahmed to discuss his team’s discovery that Mars’ iconic red dust is likely dominated not by hematite but by a hydrated mineral called ferrihydrite. This subtle but significant shift in understanding could reshape what we know about Mars’ climate history and its potential for past habitability. Then, Sarah and Bruce Betts, Planetary Society chief scientist, revisit one of the most famous Martian discoveries: Opportunity’s hematite-rich “blueberries,” which also told a compelling story about water on the Red Planet. Discover more at: https://www.planetary.org/planetary-radio/2025-why-is-mars-redSee omnystudio.com/listener for privacy information.
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What does Mars's reddish hue have to do with its watery history?
We'll talk about it, this week on Planetary Radio.
I'm Sarah Al-Ahmed of the Planetary Society, with more of the human adventure across our solar system and beyond.
Mars has been red for billions of years, but scientists may have finally cracked the case on what iron compound actually gives it that color.
This week I speak with planetary scientist Adomas or Adam Valentinas from Brown University.
He's the lead author on a new study that suggests that Mars' surface dust is dominated not by hematite as we long believed, but by a different water-rich mineral, ferrohydrite.
What does that mean for Mars' watery past?
We'll get into the science, the implications for future human explorers on Mars, and what
it tells us about the Red Planet's timeline for habitability.
Then we'll revisit one of the most iconic discoveries in Martian history, the hematite
blueberries found by the Opportunity Rover in What's Up.
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For decades, scientists have studied
the red dust coating Mars
and developed a strong working
hypothesis about what gives the planet its distinctive color.
The leading idea was that iron in the soil reacted with small amounts of water and oxygen
over long periods to form hematite.
It's a familiar form of iron oxide, or rust, that we have here on Earth.
This fits well with our broader understanding of Mars as a cold, dry planet that once held water
but lost it billions of years ago.
Earlier studies of iron oxide and Martian dust,
based primarily on spacecraft observations,
did not detect any water bound within the mineral structure.
This led researchers to conclude
that the dust must be composed of an anhydrous hematite,
anhydrous meaning it doesn't contain any water.
The hypothesis was that hematite formed
under dry surface conditions through reactions
with the atmosphere long after Mars's early wet period ended.
But science is constantly evolving
and new data adds an important layer to the story.
Recent findings led by planetary scientist Adam Valentinus,
who's a post-doctoral fellow
at Brown University and formerly at the University of Bern in Switzerland, suggest that the red
dust might actually be dominated by a different kind of iron oxide, ferrohydrite. That's
a mineral that holds water in its structure. Adam's team combined orbital and rover data
with carefully controlled lab experiments. By simulating Martian dust and analyzing how different iron-bearing minerals behave in
Mars-like conditions, he and his colleagues discovered that ferrohydrite provides a much
better match to what we actually see on the planet's surface today.
This discovery doesn't overturn what we know.
It deepens our understanding.
It suggests that Mars may have rusted much earlier than we previously thought,
while liquid water was still present, and that the red dust we see today is a relic
of a wetter, more complex climate history. Adam's team's new paper, called Detection
of Ferrohydrite in Martian Dust Records Ancient Cold and Wet Conditions on Mars, was published
on February 25, 2025 in Nature Communications.
Hi, Adam.
It's wonderful to have you on to talk about this.
Hi, Sarah.
I'm very happy to be here.
Almost everybody knows that Mars is red.
Even children know that it's the red planet, but trying to figure out why Mars is red turns
out to be way more complicated than we thought.
When did you first think to question
this long standing idea that Mars is red
because of hematite?
Yeah, so I was thinking about this question
during my PhD thesis time.
I was, I started my PhD in the University of Bern
in Switzerland back in 2018.
And perhaps during midway towards the completion of my PhD thesis, I was reading these papers and also textbooks actually on the exploration of Mars and what we know about the surface, the surface composition, physical properties and mineralogical properties. And, you know, I was kind of inspired
by the wealth of knowledge that has been generated,
you know, for decades since the age
and the birth of spacecraft observations
and the exploration of Mars since like 1960s.
And the question of why Mars is red has been, you know,
tackled by several authors and several scientists.
And, you know, I, when I was reading the literature and, you know, comparing what we know now and what
we knew before, I kind of noticed that there are still, you know, unanswered questions about the
composition of Mars and especially the composition of the Martian dusts. You know, the dust is the carrier of the color
of this rust mineral.
And then I decided to, you know, reinvestigate
and revisit this problem that's been discussed
since the 60s.
And yeah, and then, you know, as I revisit it,
I started seeing something interesting.
So we can talk about this as well later. Yeah.
Well, your paper suggests that ferrihydrite
is the reason why Mars is red and not hematite,
as we originally thought.
Can you explain the differences between these two compounds?
Yes.
Both of them are iron oxides.
So as you look at, for example, metallic surfaces on Earth,
they rust. So it's
a similar process that's happening on Mars. You need the material that has iron, and this iron is
a certain kind of specific chemical composition that changes its properties when exposed to oxygen
and water. And it's then this iron forms this iron compound known as iron oxide. And these two
minerals, so ferrohydrate and hematite, they are different because hematite does not contain
water in this chemical structure and ferrohydrate contains water in its chemical structure. So that's
why it's called ferrohydride, meaning it hydrates water
containing. And by looking at, you know, and by understanding which type of iron oxide flavor
there is on Mars, we can tell about the environmental conditions and, you know,
and the question of if there was liquid water, for example.
What conditions are necessary for
ferrohydrate to form versus this hematite? Yeah, so hematite was thought to form,
well hematite can form actually in several different environments, but the environment that was
kind of canonically favored, it was an environment that was water poor, so there was, people thought
there was no liquid water that
would could interact with this with these iron minerals. So for example, basalt, basalt is type
of volcanic rock that contains iron. And you know, they thought that you can form a hematite just by
oxidizing magma. So as magma erupts on the surface of Mars, maybe there's some traces, amounts of oxygen, and that forms this hematite.
But ferrohydrate on the other hand is formed,
especially on earth in environments that are water rich,
you need liquid water and you need also oxygen.
So on earth that you need atmospheric oxygen
for ferrohydrate to form and water.
And it can be found in iron you know, iron rich streams, aquifers,
it can be found in on the ocean floors, it can be found in lakes, it can be found, you know,
even in, you know, sewage waters of iron mines. And so it's a widespread mineral. But the thing
is with ferrohydrate, it's a very young mineral.
Hematite, on the other hand, it's found in old rocks. Ferrohydrate, in contrast, is a young
mineral. We thought that on Mars, the one reason that ferrohydrate could form is to have brief
interactions between liquid water and rocks, or you need very low surface temperatures and
very low water temperatures, so maybe near freezing. And you could sustain that perhaps
when you have, imagine you know these huge amounts of ice and maybe you could have
you know volcanic eruptions that would melt this ice and then this ice would be maybe very cold.
So this water would be very cold and it would form these flash floods and these flash floods
could maybe chemically weather and interact with the rocks and form ferrohydrides.
I mean there are so many different repercussions of everything you just said if this is the case. What does this do to our understanding of the timeline of water on Mars? Yeah so this is
also you know kind of an interesting question because there was this mineralogical model that
tried to, it's a great model, a lot of the observations that were made and concluded
A lot of the observations that were made and concluded based on this model are correct. But you know, with science, that's how it is always.
We have to think of scientists ever evolving and it's never static.
It's always dynamic.
You know, you have to refine and improve your theories. So what I'm saying is that with this model,
it's called the Bibering model.
It's a model that explains the mineralogical evolution
through time on Mars.
And you have the Noachian period,
you have the Sperm period, and the Amazonian period.
And for each period of these periods,
the observers and scientists
attributed a specific mineral formation.
So the Amazonian period was thought to produce hematite.
So three billion years of Martian geological evolution, the authors proposed hematite.
So they thought that maybe hematite can form early on, as I said, through magmatic and
oxidation of magma.
But over time, you can maybe oxidize very thin layers of rocks on Mars through these
traces amounts of oxygen.
And they thought that this process continued for three billion years.
But what we see is that if it's not hematite and ferrohydrite, you need liquid water.
And we know that liquid water on the surface of Mars currently is not stable, but there
was much more liquid water in the past.
There are also other multiple lines of evidence that also support this.
So we're not the first to say that there was liquid water in the deep Martian past.
But what we are saying is that the dust
and this rust mineral formed long ago
and it's not a contemporaneous recent geological process
that formed this mineral.
So basically we're pushing the timeline back
and saying that in the past, maybe 3 billion years ago,
there was interaction between liquid water and volcanic rocks. It formed this rust mineral.
And then over time, Mars lost its atmosphere. It became hyperarid. And once you have a hyperarid
environment, you can create dust because through erosion,
wind erosion, you can erode rocks and surface materials.
And as you erode, you make this dust.
And on earth, for example,
we know that's a higher desert
or any type of desert environment that is very arid.
And if there's no rainfall, dust accumulates.
And as there's no liquid water, no
precipitation, dust can accumulate and on Mars it is dust and gets spread around by winds and the
global dust storms. So and basically that's how this characteristic red hue arises on Mars is
through erosion of these ferrohydrate-rich rocks. That was kind of the
concept model that we proposed in our study. That is interesting because I was going to ask,
you know, if there was water on Mars in large amounts, it would be in certain locations,
which means that you would end up with some places with way more of this ferrohydrate versus other
locations. But if Martian dust storms are actually the thing knocking it around, that would explain why the entire planet ended up red instead of it
just being congregated in areas, which is almost unfortunate because it would give us an even more
deep understanding of where water was localized on Mars during those times.
Yeah, this is a very good point. You know, dust is obscuring the signal. It's, it's piloting a lot, you know, there are source regions
and there are also regions where it accumulates.
And that really makes it difficult for us to understand
where these very hydrate rich rocks are.
But our team is confident that there are some tools
and instruments that can help us address this question.
So this is actually something we're thinking about for the next project.
Well, this study combined spacecraft data from Mars Express, the Trace Gas Orbiter,
Mars Reconnaissance Orbiter, and of course the rovers as well, Curiosity, Opportunity, Perseverance.
How did you bring together so many different sources to make this discovery? Yeah, so, you know, in science, if you find something interesting, you always need to
provide solid evidence.
And the more evidence you can provide, the better because especially if you're finding
something that contradicts a form of theory, you need to build confidence in your result,
in your conclusions. So what I did is,
you know, I looked at other, not only, well, I looked at multiple data sources, as you just mentioned,
I also, you know, not only I used spacecraft observations and data, I used also rover
observations and laboratory experiments. And the exciting thing is that all of these instruments and
all of these data, they supported the initial observation and the initial conclusion that
ferrohydrate is the dominant iron oxide present in the Martian dust.
What would you say are some of the biggest challenges of actually trying to figure out
the composition of this dust using instruments in
space or even on the ground? Because we can't, you know, obviously we don't have more sample return
yet. So that's a little challenging. That's all I would say that the biggest challenge is,
is probably, you know, learning all these different instruments and understanding the data,
because to understand the data, you need to know how the instrument functions,
what are the caveats, what may be the likely artifacts,
and difficulties in working with the data.
So I think none of these challenges cannot be overcome
with the work and just perseverance and motivation.
So step by step, as I started my PhD thesis,
I, you know, or this project during my PhD thesis,
I continued working on this during my postdoc time.
So at Brown University with Jack Mustard as my supervisor.
And, you know, you just need time and you just need work
and things, you know, go your way if you just persevere. So this project
took me about three years to complete, actually. Yeah. Oh, wow. And clearly understanding how these
instruments work was really pivotal to the way that you analyze the samples in the lab,
because you didn't just use, you know, our normal methods of analyzing these things in the lab,
you wanted to mimic the way that spacecraft and rovers would do this kind of measurement on Mars to actually compare the two. What was that
process like? So one of the established methods in Mars observation or remote sensing observations
of Mars is to acquire a spectra of the Martian surface. So a spectrum is basically, it tells you
how much of light is reflected at different wavelengths.
And by, you know, the shape and absorption features
and the amount of light basically that gets reflected,
you can, from the surface of a planetary material,
you know, on planetary surface such as Mars,
you can tell something about the composition of the surface of a planetary material such as Mars, you can tell something about the composition
of the surface. However, if you compare these observations from done by spacecraft and rovers,
as you mentioned, you're not there. We don't have the samples here on Earth, so we cannot compare
directly. So we have to make our own simulants. So in the lab, you know, we synthesized with the
help of one of my colleagues, these different iron oxides. And actually, I didn't mention this, but
on earth, there are at least 10 or more iron oxides. So these are these different flavors
of iron oxides. So I looked at all of them in the lab and I was mixing them with the basalt
and these mixtures. Then we analyzed them using reflectance spectrometers. So similar type of
instruments that are on the rovers and on the spacecraft and then that gives us direct comparison
in understanding what is the actual composition of the Martian dust, you know, it helps us to really pin it down and understand,
you know, what are the major mineralogical phases present in the Martian dust.
Martian dust is really fine. How did you go about getting these tiny, tiny, tiny little dust grains?
Yeah, so that's another thing that we did. Not only we, you only we looked at different minerals, but we also looked
at physical properties. So we know that the Martian dust is extremely fine just because it's
sticky. You can see it in the rover images, you know, all this reddish hue. It collects on
solar panels. Several rovers on Mars have been really suffering because of this dust because it just, you know,
covers the solar panels and then instruments, there's no energy
generation and these rovers just, you know, they just stop
functioning. So, so it's everywhere. And this small
particle size is also has an effect on the spectral
properties. So it has an effect on the way light is reflected
from the surface.
So basically to mimic these particle sizes, we use this advanced machine in collaboration with our colleagues at the University of Grenoble in France.
We were grinding our powders. So we really approached particle sizes of close to,
or even smaller than a human hair,
about 60 times smaller than a human hair.
And so these particles are really, really fine.
And we did see that actually after grinding,
the results were fitting much better
to the actual Martian observations.
Were there any things that were actually mismatched
between this combination of ferrohydrite and
basalt with what we actually see on Mars?
You know, science is, that's the beauty of science.
It's very difficult or maybe even impossible to always have a perfect match.
So we did see, for example, that there are these effects in a near-infrared range.
So what we focused on in our study specifically was the visible range.
But we also looked at the near-infrared range, which is basically longer wavelengths of light.
We saw that there are these effects that may result from the way how particles and powders
that may result from the way how particles and powders
agglomerates and cements to each other. And you may see subtle differences in the shape
and the slope of the continuum.
So this is basically a fancy term for a feature
who was part of the spectrum.
And if it's inclined or slightly, if there's a downturn.
So we saw that between our data and the observations, there's inclined or slightly, or if there's a downturn.
So we saw that, you know, between our data and observations,
there's a slight difference, but this is quite minor.
Well, it's one thing for ferrohydrate to form on Mars,
but as you said, it's a totally other thing
for it to remain stable for that long period of time.
So how did you test to see whether or not
this would break down in Martian conditions?
Yeah, so this was another set of experiments that we conducted and this was in collaboration with
our colleagues at the University of Winnipeg in Canada. So as you can see, as you know have
noticed, this is a quite a laboratory-led project. As I said, you know, have noticed this is a quite a laboratory led project.
As I said, you know, I worked, I started working at the University of Bernd, then the University of Grenoble,
Brown University, and then the University of Winnipeg.
So basically what we did is we sent a few samples to our colleagues at the University of Winnipeg,
and they have a Mars chamber.
So basically a Mars chamber is basically
a kind of a closed system,
a closed container where you put the samples in.
You can regulate the environmental conditions such as temperature,
relative humidity, you can also shine
the samples with ultraviolet light and simulate the radiation environment
that's present on Mars.
And then you can test how all of these parameters, how they affect, how they change different
properties of your samples.
So what we're interested in, in our case, was to look at the mineralogical structure of
ferrohydrates, you know, how the atomic structure, basically how the atoms of
ferrohydrates and if the atoms and the structure, atomic structure in
ferrohydrate is affected by the Martian conditions, similarly the Martian
conditions, because there was this idea that ferrohydrate is not stable on the
Martian surface and that it would change, you know, that it would not be present
and it would crystallize and change into, for example, a hematite. That was like
one of the prevailing ideas. So we, you know, we decided to test this hypothesis
and what we saw was that there was no change. As you put this
ferrohydrate in this chamber, you know, you cram down the humidity, you fill it
with carbon dioxide, you know, you shine, you know, ultraviolet radiation.
Nothing happened. We saw that ferrohydrate is the crystal structure of
ferrohydrate remains the same same because we also did another measurement just after
dehydration. So this experiment was dehydrating the sample and then we did x-ray diffraction
measurements. So we took an x-ray diffraction pattern of air hydrate before the experiment
and then we took a second pattern after the experiments. And then again, comparing these two data sets,
we saw no difference.
So ferrohydrate is poorly crystalline,
it's very disordered mineral,
and there's no change in ferrohydrate structure.
But we are talking about timescales
that are like billions of years long.
Can we extend that out that far?
Very good question.
This is actually one of the questions
that not only a few of my co-authors asked, extend that out that far? Very good question. This is actually one of the questions that
not only a few of my co-authors asked, but also the reviewers asked during the review process. So what I did is I looked at the literature and at the theory. So there's this law or equation
called Arrhenius equation, and it's quite widely used in the chemistry and the
geochemistry communities and basically it tells you that certain
kinetic reactions are very dependent on temperature, actually very dependent, so
super sensitive and as you so we have to think you know about the
temperature regimes on Mars. Mars is very cold right now. The average surface temperature is minus 70 C,
so Celsius, so very cold,
well below freezing temperatures.
And these actually surface temperatures,
they slow down a lot of kinetic reactions,
a lot of these reactions that will be happening on Earth,
but they don't happen
or are extremely slowed down on Mars.
And basically I employed these theoretical calculations, which also suggested that ferrohydrates
is basically in some sort of, it's in a frozen state.
It will not crystallize and change into other iron oxides just because
it's very dry and also very cold. And this was great because these theoretical calculations,
they agreed with our laboratory experiments. And if we combine this with the understanding
of the conditions under which these two different iron compounds form, this could potentially tell us a lot about whether or not Mars had this warm
kind of, you know, wet past or if it was mostly cold and icy. Yes, so we discussed this in the in
the paper as well because we know from, as I mentioned before, from several past studies that investigated
the mineralogy of the Martian surface, both from orbit and from ground.
They have identified various hydrated minerals, such as clays and sulfates.
This has been known since maybe 2005, so now 20 years we have known that there are all
these other hydrate minerals.
So we discussed that perhaps these clays and sulfates, they perhaps formed before ferrohydrides.
So you could have had maybe warmer conditions early on, but then the surface environment started to become more cold and dry.
And perhaps the formation of ferrohydrates suggests that it formed during the latest gulps of water in Mars history. Maybe it was the last stage of these mineral formations as water was becoming colder, more brief, maybe more episodic,
and then at some point completely dry. Both of these iron compounds also
require some kind of oxidizing environment in order to form. And we
don't have a lot of oxygen
in the Martian atmosphere today,
but there is some indication
that there was more oxygen in the past.
I think there have been some studies
on like manganese oxides and other things found on Mars
that suggests that it did have a lot more oxygen
in the past, but what other sources of oxygen
could potentially lead to the creation
of these chemicals other than that?
Yeah, great, great point. This is also something that we have discussed quite a lot in the team,
but also with several scientists in the community. So on Earth, as you mentioned,
you know, these iron oxides, they form because of atmospheric, well, they require atmospheric
oxygen and the Earth's atmosphere is very oxygen rich,
which is not the case for present-day Mars.
However, in the past, there may have been a bit more oxygen, but we had to agree that
perhaps free oxygen, free atmospheric oxygen was not required for ferrohydrate formation.
And you know, there are alternative chemical pathways that will result in ferrohydrate formation. So, for example, you can create
oxidants in the water just by shining a UV light. The process is called photo oxidation. So as you
shine UV at the water, it creates these OH radicals. So these compounds that can react
with iron and oxidize the iron just in, so you
just need the liquid water.
You can also form some traces of free oxygen by photolysis, so if you're shining a UV light
at gas molecule, water molecules in the vapor form, it splits them up into hydrogen and
oxygen and perhaps some of this oxygen, free oxygen,
then created by photolysis can react with iron and oxidize it.
So what I'm trying to say is that there are multiple pathways how you can oxidize iron
minerals and manganese, for example, manganese-rich materials, and perhaps large amounts of
oxygen is not required. So, but this is, again, this is something that we are
thinking about for future work and maybe, you know, we find a way how to distinguish between
these varying hypotheses. We luckily have some really wonderful missions coming up that could help us try to sort some of this out.
I'm really looking forward to the European Space Agency's Rosalind Franklin rover,
but also we're really pulling for that Mars sample return mission over here
because getting those samples could potentially shed light on a lot of these puzzles
that are going to be really difficult to solve otherwise.
Yes, definitely for Mars exploration, you know, these are exciting times.
And the Rosen Franklin rover includes a drill,
so they can actually, you know, drill into the subsurface
for up to, I think, two meters depth.
So you could potentially look at if there's a difference in oxidation
of the surface materials
as you go and drill deeper into the Martian subsurface.
And that could also actually tell us about, you know, what kind of oxidizing environment was present on ancient Mars,
but also modern Mars, because Mars is, although it has a very thin atmosphere,
there are still processes happening on the surface
that are interesting and we can investigate.
We'll be right back with the rest of my interview
with Adam Valentinus after this short break.
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It's funny that after all this time, all of this research on Mars is so much that we still don't
understand. Do you think that this finding suggests that there's potentially other minerals and
processes on Mars that we might have completely misunderstood? Well, we know a lot about Mars and
I think it's quite possible that there are things
that perhaps we have not thought about and you know they are just there in the data which just
there's you know we need someone who looks and revisits all these great data sets that we have
for Mars and I think it's quite likely that you know we could find something that's not been thought about and not discovered.
Well, it feels weird to characterize it as completely misunderstanding.
I mean, even in this case, we're literally just debating over whether or not it's this flavor of iron compound versus this flavor of iron compound.
Like, we understand a good amount of the way that this is falling out.
It's just about which one and what timing and what initial conditions, which is going to take us a bit to figure out. But I mean, it's quite remarkable
that we're at this point.
Yeah. And, you know, and one of the reasons why sometimes, you know, we find something
new is because our instruments and our data sets are improving. So, you know, the early
Mars exploration was done using ground-based telescopes, for example. And, you know, the early Mars exploration was done using ground-based telescopes, for example,
and, you know, we did not have spacecraft or rovers there.
And these scientific conclusions and observations were quite limited in the beginning.
So as our instruments are improving and as our data sets are improving,
we can actually refine a lot of these questions and advance our knowledge of Mars' geological history and evolution and the environments that
were present not only on present-day Mars but also ancient.
If this is the case then Mars would have rusted when it still had water present
on its surface and and that means the red color is more of a sign of a wetter
past than this slow oxidation process. What do you think this suggests about the history of habitability on Mars?
So life as we know it requires liquid water. NASA even has a mantra called follow the water.
So for a Martian exploration, tracing the water and understanding where the water was
exploration, tracing the water and understanding where the water was is quite important, especially for habitability question. So by identifying that the Martian dust or this iron mineral contains
water that tells us that liquid water was required and by this inference you can maybe argue that
And by this inference, you can maybe argue that that raises the habitability potential of Mars, because now, you know not only carbon dioxide, but they are composed of water. You have these clay minerals and sulfates that I talked about, which have been discovered in the past.
The dust is a carrier also of hydration and evidence for liquid water.
I think all of these lines of evidence suggest that the conditions for life may have been
present on Mars.
Now we just need to basically find the evidence, which is the most difficult part of Martian exploration.
However, we have, you know, Perseverance Rover and also Curiosity Rover who are
investigating these environments that contain liquid water and perhaps
they can address these questions. You know, I've been looking at Mars images
for most of my career but sometimes I still get excited've been looking at Mars images for most of my career, but sometimes
I still get excited just by looking at all these amazing images that have been acquired by
Perseverance Rover, but also by spacecraft data. But to note, actually, you mentioned
something interesting about human exploration of Mars. So this kind of an observation that
interesting about human exploration of Mars. So this kind of an observation that we can make
from just the evidence of ferrohydrate in the dust is that human explorers, once they land on Mars,
suppose they land somewhere where it's very dry and there's no ice in the subsurface, they could potentially use that Martian dust and ferrohydrite to cultivate this water because ferrohydrite is hydrate. So there's probably something maybe
up to an order of 10% by weight of water in this mineral structure. So you just need to heat it up
really strongly and condense the vapor, the gas released from
ferrohydrate.
And you know, you could use this perhaps as a resource.
Mark Watney would have wanted to know that during his not real time on Mars.
No, but that's a great point.
This does have some implications there then.
We're going to need that if we're going to do it, although we're also going to have
to figure out that whole perchlorate issue.
There's a lot there going on, but each and every clue that we get takes us a step closer
to being able to put humans on another world in our solar system, and that's just amazing.
But you touched on this a little bit earlier, that you do have some future plans for your
research.
Do you want to talk a little bit more about what you're going to be doing next? The discovery of ferrohydrates on Mars opens several research directions and, you know,
it raises several interesting questions. So one of the questions is constraining the timing,
so trying to understand when the oxidation happened because right now we just use the
the oxidation happened because right now we just use the abundance of liquid water on ancient Mars as perhaps the time when ferrite formed. We mentioned something about three billion years ago,
but we need to constrain this and understand how long this could have happened. Then for that,
you need to look at the geology. This is one one of the kind of the research directions that
we will take in the future. Another thing is to understand how
ferrohydrate forms. So I mentioned to you that you know on Earth there are various
environments but perhaps on Mars there are geochemical pathways that we have not thought about. So I intend to look
at ferrohydrate formation in the lab. So basically synthesize this mineral in various different ways,
exposing it to Mars-like conditions, changing the temperature, changing the atmospheric
composition, and seeing how that affects ferrohydroformation.
And from these laboratory experiments,
we can maybe understand something very fundamental
and very interesting about the surface processes
on ancient Mars.
So cool.
Good luck with all your future research.
And I'd love to know more if you actually
do these experiments and find out something cool. Because I'm just kind of mind blown that we're still in the situation where
we're still finding out cool new stuff from old data and combining it with lab results
the way that you did.
Really clever.
That's awesome.
Yeah.
Thank you so much.
Yeah, it's exciting and especially, you know, I did not mention, but the Mars Sample Return
mission hopefully will
bring back samples and in those samples you will have dust because as I mentioned dust is everywhere
it's sticking to every single you know object on the surface of Mars so you'll have some contamination
of dust and if we study you know these dust particles we can test this hypothesis and really understand if this
ferrohydride is present on the Martian surface, although I believe it is, but we always need to
test our hypotheses. But not only is it important for testing the hypothesis, but also just by
studying the chemical composition of this ferrohyrate in the return samples can tell us a lot because you can look at stable isotope measurements.
So it's basically it's a type of analysis that looks at isotopic composition of the hydrate.
And that can tell us about, you know, water temperature during the formation of a hydrate.
It can also tell us about the source of the water.
So, for example, it could tell us if it's meteoric or marine. So, you know, if it's from
precipitation or, for example, if it formed in oceans. And also it can tell us also something
about habitability because we know that on Earth microbes interact with a plethora of minerals and iron oxide, namely ferrohydride,
for example, is known to be an important agent for these microbial reactions. And, you know,
there are several different things we can test by having the MARS sample return happening and,
you know, looking at ferrohydride present in these samples.
happening and looking at the hydrogen present in these samples.
I cannot stress enough how much I want those samples to actually reach Earth.
We're, as an organization, trying to advocate as hard as we can for Mars sample return. It's going to take some time and some work, but whether or not these samples come home
sometime in the next 10 years or some other time, eventually, eventually humanity is going to get
their hands
on something from Mars
and we're gonna be able to figure out these questions.
And I'm so excited.
I just, I want it to happen yesterday
instead of 40 years in the future.
Oh yes, definitely.
I mean, the scientific community is also extremely excited
about the prospects of having the samples back.
And, you know, I hope that maybe day, if the samples are brought back,
maybe one of my future students can look into it and test these ideas.
I love that. And then they can use your research and all the other people that have come before,
combine it all together and, oh, the things we could learn.
It's going to be a beautiful future when we get all this back.
Definitely. I mean, my research is based on all the previous research from the community.
So we're standing on the shoulders of giants.
And I mean, that's how that's the beauty of science.
You're building and the future generations can also provide something very interesting.
Nice Isaac Newton reference.
Thanks for joining us, Adam. I really appreciate it and good luck in your future research. provide something very interesting. Nice Isaac Newton reference. Yes.
Thanks for joining us, Adam. I really appreciate it.
And good luck in your future research.
Yeah, thank you so much for having me. I
enjoy this interview.
If you'd like to get deeper into this
research, I've included a link to Adam's
full paper, Nature Communications,
along with a great write-up from the European
Space Agency on this week's episode page
at planetary.org slash radio.
Of course, Mars has been surprising us for decades.
One of the most memorable early clues to its watery past came from the Opportunity Rover,
which discovered tiny hematite-rich spherules scattered across the surface, nicknamed blueberries.
They told a very different part of the story, one shaped by groundwater
and chemistry. Here's our chief scientist, Dr. Bruce Betts, for What's Up.
Hey, Bruce.
Hey there, Sarah.
I'm back from my big whirlwind city adventure in D.C. and also our beautiful gala. It was
nice to see you there.
It was nice to see you there. That was actually my double.
Your clone.
I hired to go to events, yeah.
Yeah, man. You know, it wouldn't be bad to have a clone just so she could do some extra editing,
maybe go off to Mars, pop back and tell me how it was.
Sarah too.
I think this research paper is really interesting in that, like, we had a general concept of
what was going on with Martian dust, but even with all of our data, there's still some wiggle
room in the chemistry there.
So I think getting those samples back will be, honestly, very helpful.
But even so, it's not like we didn't understand what was going on with Mars.
We're just kind of refining our understanding of which particular iron oxide.
So it's cool that we're in that place.
Hardcore mineralogy.
Hardcore.
I wanted to bring this up with you because I think
even for me, one of the big things that pointed
to the fact that Mars had liquid water in the past
was this discovery that blew up in newspapers
and on social media about these so-called blueberries
on Mars that Opportunity found.
They're not actual blueberries.
I've even heard little kids ask me
why there's blueberries on Mars,
thinking that they're legit blueberries.
So I wanted to bring this up and talk a little bit
about how that relates to hematite
and this broader discovery of what kind of iron is on Mars.
So could you tell us a little bit about,
you know, what went down with Opportunity
and why was that discovery so awesome?
Okay.
First of all, what they're not actual blueberries.
Okay.
No, no, I, I know this.
So I'm going to back up a little bit and take the picture out to spirit as well.
It's for the spirit Rover.
So spirit and opportunity were sent at the same time and and landing sites, obviously two landing sites were picked. And it was interesting because
Spirit's landing site was based mostly on geomorphology. So it was put into a location
at the end of a big hundreds of kilometer long valley channel that presumably water,
liquid water flowed in and that's how they picked
where they went.
This is shortening a story that took months and years
of scientists arguing about it.
But the opportunity site was chosen based on spectroscopy
and perceived mineralogy.
So using the thermal emission spectrometer
on Mars Global Surveyor and complimentary data,
they saw one of the few places on Mars
that showed a spectra that should have corresponded
to coarse-grained hematite.
Coarse-grained hematite being a gray mineral
that you may have seen often made magnetic
and used in jewelry and things like that. Well, it turns
out that is very exciting for those playing the liquid water game, which people play because
liquid water is needed by all life on earth. And so, finding a place that seemed to have
coarse-grained hematite was a party when you're looking for water, which might have something to do with life. So when it landed, this was the era of airbag landings. So you inflate airbags around the
entire spacecraft, and when it lands, it bounces, and it bounces, and it bounces, and bounces,
bounces, bounces. It's very Tigger-like in that respect. And they referred to opportunity as being a hole in one because when it bounced after
bouncing a kilometer or two, literally, it ended up in a very small impact crater.
And so one of the first things it saw was the miniature cliffside of the impact crater
that showed exposed sedimentary layers, and it showed blueberries, which I'll get
back to, but coarse-grain hematite all over the place and this was very exciting.
But really though, the fact that they managed to get a kind of hole-in-one
after practically bubble wrapping a rover and dropping it on Mars is kind of
spectacular. It was and if you look at those initial images, it was very confusing, at least for those of
us not truly in the details of the imagery, because it looks like you've got like a 10-meter
cliff that you're looking at, and it turns out it's like 10 centimeters.
But still showed multiple sedimentary layers.
And there are these things all over, these little spheres that when you look at them particularly in a false
color they get they look bluish and in fact they are bluer they aren't really
blue but they're bluer than all the red stuff all around and it turns out the
stuff's all over where they landed when they went out and they drove on the
planes. Why is this important?
Because it's associated, again, with usually, almost always on earth with liquid water creation
and things like hydrothermal systems and the like.
So to get that instant confirmation, or practically instant, was just a wonderful contrast.
So you take spirit, spirit, it was the very end of
years into the mission where it got its most powerful examples of things that look like
they form in liquid water in terms of seeing them on the surface. Again, you've got this
huge channel flowing in. Anyway, it was groovy and as soon as they were called blueberries,
the name was stuck. But this leads me to another question, which is that if coarse-grained hematite is this
bluish color, then why would people attribute the red dust on Mars to this bluish iron oxide?
Well, it's more grayish in reality and Earth, but still, it's a valid question.
I will admit that I'm not entirely sure,
but I think it is because there is also fine-grained hematite
and permutations therein,
and that tends to be reddish on earth
and is also conforming aqueous water environments
or not as much.
It would be a different form of how you arrange the, how
you pile up the molecules in a crystalline lattice.
S. Every time I learn more about Spirit and Opportunity, I mean, I've heard this story
so many times, but it still completely blows my mind that that rover basically mission
accomplished itself on day one and then went on to have 14 years almost on Mars. So far beyond
what we ever thought it was going to be able to do. I don't know. I just I'm really looking
forward to the day that we have these kinds of rovers on every single terrestrial world because
just imagine what we could learn with one of these going around on Mercury or even the moons out there.
It would be so cool. Why don't we go into our random space fact of the week?
So I'm going to talk about ancient astronomers and their accomplishments. So the Mayans
have got a lot of bad rap for their calendar and have other reasons for bad raps. But in terms of science and
astronomy, they were amazingly spot on for how little they had in terms of equipment, essentially
none. They were able to predict eclipses of solar and lunar eclipses accurately. They have their setups of, for example, in Chichen Itza in the Yucatan Peninsula,
you have things where on the equinox a shadow appears. I don't know if you've ever seen the
picture of the castle of Castillo, the pyramid, and the shadow appears looking like a feathered
serpent it was designed for, but it's on the equinox that it highlights
that symbol. And they also had an observatory aligned to study Venus's movements. Now, an
observatory didn't have a telescope in it that we are aware of, but was a isolated place that is
for astronomical observation. There you go, Mayan astronomers, well played
sirs, well played. Good stuff.
I mean, that's dedication right there. Learning enough about space that you can track that
kind of stuff so you can build your buildings in such a way that on one particular day something
happens. I was wowed by that when I was a kid in my hometown. We had a building, it
was an old California mission
where the sun at its peak when it hit that meridian
in the sky would shine right through a hole in the wall
on the winter solstice.
I mean, just for that one moment,
that is a really beautiful dedication
and just a statement about how deeply these things
are embedded in different people's cultures.
And there are civilizations you know, civilizations,
various places that had this type of thing. And of course, one of the fundamental things
was understanding the calendar to understand, assuming you're at the age of agriculture,
to understand when you should be planting crops and what the sun's doing and things like that.
Anna Scalise Right. And now people can't even see
the night sky because we have too many lights.
Yeah, but we have professionals who are now far more adept at those things.
That's fair.
Because, you know, satellites. So lights in the sky, I can't see as well.
Satellites, no, no, well, very little atmosphere, depending where you are.
Now, what is this? I'm trying to be the positive one. Come on.
Don't put me in that position.
Too late now, Bruce. Now you're the positive one. Deal with it.
Oh, I would like to. I think that's a very great opportunity for me going forward.
All right, everybody, go out there, look up the night sky and think about the most positive thing that you have thought of when looking up at the night sky.
Thank you and good night.
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